Acetylene-allene rearrangements. Reactions of trivalent phosphorus chlorides with α-acetylenic alcohols and glycols
AP Boisselle, NA Meinhardt
Index: Boisselle,A.P.; Meinhardt,N.A. Journal of Organic Chemistry, 1962 , vol. 27, p. 1828 - 1833
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Citation Number: 82
Abstract
The reaction of trivalent phosphorus chlorides with or-acetylenic alcohols in the presence of an organic base produced allenic, pentavalent phosphine oxides.-4 number of phosphinates and phosphonates containing both the allenic and acetylenic structures are also described for the first time. Infrared spectra of compounds of this type indicate intermolecular hydrogen bonding between the ethynyl hydrogen and the phosphoryl ...
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