Monothiocarbonates and their oxidation to disulphides
CN Murphy, G Winter
Index: Murphy,C.N.; Winter,G. Australian Journal of Chemistry, 1973 , vol. 26, p. 755 - 760
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Citation Number: 20
Abstract
Abstract The preparation, properties, and oxidation of potassium methyl to hexyl mono- thiocarbonates and of dipotassium butyl bis (monothiocarbonate) are reported. The oxidation product of the latter is a dimer. Some nickel, lead, copper, and silver complexes were isolated. The ability of monothiocarbonates to form metal complexes lies between alkyl carbonates and dithiocarbonates. Copper (I) ethyl monothiocarbonate is a tetramer.
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