Ring-Size Effects in the Neophyl Rearrangement. VII. 1 The Peroxide-Induced Decarbonylation of (1-Phenylcyclopropyl)-and (1-Phenylcyclobutyl) acetaldehydes
JW Wilt, LL Maravetz, JF Zawadzki
Index: Wilt,J.W. et al. Journal of Organic Chemistry, 1966 , vol. 31, p. 3018 - 3025
Full Text: HTML
Citation Number: 30
Abstract
The syntheses of (1-phenylcyclopropy1) acetaldehyde 2 and (1-phenylcyclobuty1) acetaldehyde 3 are described in detail, together with certain other reactions of possible interest. The aldehydes were decarbonylated under freeradical conditions using di-t-butyl peroxide (DTBP) as the initiator and in several different reaction environments, uiz., neat aldehyde, aldehyde 1 M in solvent, and aldehyde in the presence of a mercaptan. The ...
Related Articles:
Electrical effects of cycloalkyl groups
[Hahn,R.C. et al. Journal of the American Chemical Society, 1968 , vol. 90, p. 3404 - 3415]
[Bailey, William F.; Gagnier, Paul R.; Patricia, Jeffrey J. Journal of Organic Chemistry, 1984 , vol. 49, # 12 p. 2098 - 2107]
[Kitahara,Y. et al. Journal of the American Chemical Society, 1960 , vol. 82, p. 3106 - 3111]
Preparation of Organomercury Compounds
[Shabarov,Yu.S. et al. Doklady Chemistry, 1971 , vol. 198, # 4 p. 477 - 479 Dokl. Akad. Nauk SSSR Ser. Khim., 1971 , vol. 198, # 4 p. 859 - 861]
[Bailey, William F.; Gagnier, Paul R.; Patricia, Jeffrey J. Journal of Organic Chemistry, 1984 , vol. 49, # 12 p. 2098 - 2107]