Journal of the American Chemical Society

Radiation-induced Addition of Hydrogen Sulfide to Substituted Acetylenes. Synthesis of Vinylthiols

FW Stacey, JF Harris

Index: Stacey,F.W.; Harris,J.F. Journal of the American Chemical Society, 1963 , vol. 85, p. 963 - 965

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Citation Number: 33

Abstract

Free-radical additions of thiols and of hydrogen sulfide to olefinic compounds have been studied extensively during the past twenty-five years,'but additions to acetylenic compounds have received far less attention. The “thermal” addition of p-thiocresol to phenylacetylene to give a quantitative yield of a mixture of the cis and trans isomers of p-tolyl P-styryl sulfide2 was apparently the first example of a free-radical chain addition of a thiol to an acetylene. ...