Boron photochemistry: X. Anilinodiaryl boranes: their synthesis and photochemistry

ME Glogowski, PJ Grisdale, JLR Williams…

Index: Glogowski,M.E. et al. Journal of Organometallic Chemistry, 1973 , vol. 54, p. 51 - 60

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Citation Number: 23

Abstract

Abstract A series of stable anilinodimesitylboranes was synthesized. Their mass spectra and nuclear magnetic resonance spectra were studied. The photocyclization of these compounds in the presence of iodine is accompanied by a facile 1, 2-methyl migration. The structure of the products has been assigned on the basis of spectral evidence and degradation studies.