Organocatalytic enantioselective decarboxylative aldol reaction of malonic acid half thioesters with aldehydes
…, JH Sim, JW Lee, B List, CE Song
Index: Bae, Han Yong; Sim, Jae Hun; Lee, Ji-Woong; List, Benjamin; Song, Choong Eui Angewandte Chemie - International Edition, 2013 , vol. 52, # 46 p. 12143 - 12147 Angew. Chem., 2013 , vol. 125, # 46 p. 12365 - 12369,5
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Citation Number: 32
Abstract
The direct asymmetric aldol reaction is one of the most powerful and fundamental tools for forming new carbon–carbon bonds and chiral hydroxy functional groups simultaneously.[1] Inspired by nature, the development of prefunctionalized metal enolates and metal Lewis acids to mimic type II aldolases have provided a general solution to accessing enantioenriched β-hydroxy carbonyl compounds in cooperation with chiral auxiliaries and ...
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