Canadian Journal of Chemistry

Reactions of Phosphorus Pentachloride with Ethyl-, Vinyl-, and Ethynyl (trichloromethyl) carbinol and with 1, 1, 1-Trichloro-3-nonyn-2-ol

EW Reeve, TF Steckel

Index: Reeve,E.W.; Steckel,T.F. Canadian Journal of Chemistry, 1973 , vol. 51, p. 2017 - 2023

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Citation Number: 4

Abstract

Reactions of phosphorus pentachloride with ethyl (trichloromethyl) carbinol (2),(trichloromethyl)-vinylcarbinol (7), ethynyl (trichloromethyl) carbinol (11 a), and 1, 1, 1- trichloro-3-nonyn-2-ol (11 b) have been studied. Whereas the reaction of phenyl (trichloromethyl) carbinol with phosphorus pentachloride leads to a nearly quantitative replacement of the hydroxyl group by chlorine, the reactions of the aliphatic ( ...