A practical method for the large-scale preparation of [N, N'-bis (3, 5-di-tertbutylsalicylidene)-1, 2-cyclohexanediaminato (2-)] manganese (III) chloride, a highly …

JF Larrow, EN Jacobsen, Y Gao, Y Hong…

Index: Larrow, Jay F.; Jacobsen, Eric N.; Gao, Yun; Hong, Yaping; Nie, Xiaoyi; Zepp, Charles M. Journal of Organic Chemistry, 1994 , vol. 59, # 7 p. 1939 - 1942

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Citation Number: 746

Abstract

The use of catalytic asymmetric reactions for the synthesis of highly enantiomerically enriched chiral compounds is of growing importance in organic chemistry and in the chemical industry at large.'The practical utility of a catalytic asymmetric method is closely tied to the accessibility of the catalyst and can be severely undermined if the process for preparation of the catalyst proves too costly or technically-difficult for large-scale ...