Functionalized 13-crown-4, 14-crown-4, 15-crown-4, and 16-crown-4 compounds: synthesis and lithium ion complexation

…, DA Babb, B Son, RA Bartsch

Index: Czech, Bronislaw P.; Babb, David A.; Son, Byungki; Bartsch, Richard A. Journal of Organic Chemistry, 1984 , vol. 49, # 25 p. 4805 - 4810

Full Text: HTML

Citation Number: 63

Abstract

Seven novel (benzy1oxy) methyl-substituted crown ethers with four ring oxygens and 13-, 14- , 15, and 16-membered polyether rings are synthesized and their lithium and sodium cation- binding abilities are assessed by solvent extraction of the aqueous alkali metal picrates. Strongest lithium ion complexation is observed with [(benzyloxy) methyl]-l4-crown-4 compounds.

Related Articles:

Substituted diether diols by ring-opening of carbocyclic and stannylene acetals

[Martinez-Bernhardt, Rolando; Castro, Peter P.; Godjoian, Gayane; Gutierrez, Carlos G. Tetrahedron, 1998 , vol. 54, # 31 p. 8919 - 8932]

Steroidal bivalent ligands for the estrogen receptor: design, synthesis, characterization and binding affinities

[LaFrate, Andrew L.; Carlson, Kathryn E.; Katzenellenbogen, John A. Bioorganic and Medicinal Chemistry, 2009 , vol. 17, # 10 p. 3528 - 3535]

Molecular design of crown ethers. VII. Syntheses and cation selectivities of unsubstituted 12-to 16-crown-4.

[Liu, Yu; Inoue, Yoshihisa; Hakushi, Tadao Bulletin of the Chemical Society of Japan, 1990 , vol. 63, # 10 p. 3044 - 3046]

Substituted diether diols by ring-opening of carbocyclic and stannylene acetals

[Martinez-Bernhardt, Rolando; Castro, Peter P.; Godjoian, Gayane; Gutierrez, Carlos G. Tetrahedron, 1998 , vol. 54, # 31 p. 8919 - 8932]

Lipophilic crown-4 derivatives as lithium ionophores

[Kitazawa, Sadaya; Kimura, Keiichi; Yano, Hideki; Shono, Toshiyuki Journal of the American Chemical Society, 1984 , vol. 106, # 23 p. 6978 - 6983]

More Articles...