… -state properties of (coumarin-4-yl) methyl derivatives. 2. Photocleavage of selected (coumarin-4-yl) methyl-Caged adenosine cyclic 3', 5'-monophosphates with …

T Eckardt, V Hagen, B Schade, R Schmidt…

Index: Eckardt, Torsten; Hagen, Volker; Schade, Bjoern; Schmidt, Reinhardt; Schweitzer, Claude; Bendig, Juergen Journal of Organic Chemistry, 2002 , vol. 67, # 3 p. 703 - 710

Full Text: HTML

Citation Number: 114

Abstract

A series of axial and equatorial diastereomers of (coumarin-4-yl) methyl-caged adenosine cyclic 3', 5'-monophosphates (cAMPs), 1-6, having methoxy, dialkylamino, or no substituent in the 6-and/or 7-positions, and their corresponding 4-(hydroxymethyl) coumarin photoproducts 7-12 have been synthesized. The photochemical and UV/vis spectroscopical properties (absorption and fluorescence) of 1-6 and 7-12 have been examined in ...