Oxidation of isobutene and methylenecycloalkanes by palladium (II) acetate
K Kikukawa, K Sakai, K Asada, T Matsuda
Index: Kikukawa,K. et al. Journal of Organometallic Chemistry, 1974 , vol. 77, p. 131 - 145
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Citation Number: 17
Abstract
Abstract Reactions of isobutene, methylenecyclopentane, methylenecyclohexane and methylenecycloheptane with palladium acetate were studied in acetic acid at 30 to 80. Two types of oxidation were identified: acetoxylation to allylic acetates (methylenecycloheptane) and oxidative coupling to dimers (isobutene and methylenecyclohexane). A mechanistic study indicated that the former was produced by thermal decomposition of the initially ...
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