Organic letters

Oxidative Synthesis of Cyclic Acyl Aminals through Carbon-Carbon σ-Bond Activation

DL Aubele, PE Floreancig

Index: Aubele, Danielle L.; Floreancig, Paul E. Organic Letters, 2002 , vol. 4, # 20 p. 3443 - 3446

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Citation Number: 27

Abstract

Acyliminium ions can be prepared through photoinitiated single-electron oxidation reactions of homobenzylic amides and carbamates. Cyclic acyl aminals are formed when these acyliminium ions are appended to nucleophiles such as hydroxyl, ether, and sulfonamide ...