Structural characteristics of 2-halo-1, 3, 2-dithiarsenic compounds and tris-(pentafluorophenylthio)-arsen

TA Shaikh, RC Bakus, S Parkin, DA Atwood

Index: Shaikh, Taimur A.; Bakus II, Ronald C.; Parkin, Sean; Atwood, David A. Journal of Organometallic Chemistry, 2006 , vol. 691, # 9 p. 1825 - 1833

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Citation Number: 26

Abstract

The combination of various dithiols and AsX3 (X= F, Cl) produces the series of cyclized halo- arsenic dithiolate compounds: 2-chloro-1, 3, 2-dithiarsolane [AsCl (SCH2CH2S)](1), 2-iodo- 1, 3, 2-dithiarsolane [AsI (SCH2CH2S)](2), 2-chloro-1, 3, 2-dithiarsenane [AsCl (SCH2CH2CH2S)](3), 2-iodo-1, 3, 2-dithiarsenane [AsI (SCH2CH2CH2S)](4), 3-chloro-4H, 7H-5, 6-benz-1, 3, 2-dithiarsepine [AsCl (SCH2) 2 (C6H4)](5), 1, 2-bis-dithiarsolan-2- ...