Studies on the rearrangement of ortho-nitrobenzylidenemalonates and their Analogues to 2-aminobenzoate derivatives

E Lewandowska, S Kinastowski…

Index: Sawai, Yasuhiro; Yamane, Taihei; Ikeuchi, Motoki; Kawaguchi, Shinji; Yamada, Masatoshi; Yamano, Mitsuhisa Organic Process Research and Development, 2010 , vol. 14, # 5 p. 1110 - 1117

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Abstract

... α- addition of the thiol to the α,β-unsaturated carbonyl com- pounds, a process that is ... The organic layer was washed (NaHCO3–H2O, brine), dried (MgSO4) and volatiles were evaporated ... Procedure A Titanium(IV) chloride (1.1 mL, 10 mmol) in carbon tetra- chloride (2.5 mL) was ...

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