Copper-catalyzed intermolecular C–H amination of (hetero) arenes via transient unsymmetrical λ3-iodanes
I Sokolovs, D Lubriks, E Suna
Index: Sokolovs, Igors; Lubriks, Dmitrijs; Suna, Edgars Journal of the American Chemical Society, 2014 , vol. 136, # 19 p. 6920 - 6928
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Citation Number: 36
Abstract
A one-pot two-step method for intermolecular C–H amination of electron-rich heteroarenes and arenes has been developed. The approach is based on a room-temperature copper- catalyzed regioselective reaction of the in situ formed unsymmetrical (hetero) aryl-λ3- iodanes with a wide range of primary and secondary aliphatic amines and anilines.
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