Tetrahedron letters

Regiospecific nucleophile-induced fragmentation of α, α-dichloro-β-iminocarbonyl compounds

N De Kimpe, R Verhe, L de Buyck, N Schamp

Index: De Kimpe, Norbert; Verhe, Roland; De Buyck, Laurent; Schamp, Niceas Tetrahedron Letters, 1985 , vol. 26, # 22 p. 2709 - 2712

Full Text: HTML

Citation Number: 6

Abstract

Retro-ene type reactions have been studied already extensively in the lite- rature. Major attention has been given to substrates containing an olefinic double bond (1 : Z=CR1R2; homoallylic alcohols), while many exym;les of the fragmentation of B-hydroxycarbonyl compounds 2 (Z=O) are known - (the base- induced fragmentation of f3-ketocarbonyl compounds also belongs to this category of reactions). Mechanistic studies have revealed that these thermal ...

Related Articles:

Identification of degradation products occurring in acidic solutions of a 21-aminosteroid (tirilazad)

[THE UPJOHN COMPANY Patent: EP263213 A1, 1988 ;]

Influence of carbonate ester molecular structure on compression ignition combustion and emissions

[Bigley,D.B.; Wren,C.M. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1972 , p. 2359 - 2361]

Selenium Catalyzed Synthesis of of Carbonates. The Reaction of Alkoxide with Carbon Monoxide and Oxygen in the Presence of Selenium

[Kondo,K. et al. Bulletin of the Chemical Society of Japan, 1975 , vol. 48, p. 108 - 111]

Synthesis and kinetics of decomposition of di-tert-butyl tricarbonate, di-tert-butyl dithioltricarbonate, and the related dicarbonates

[Dean,C.S. et al. Journal of Organic Chemistry, 1970 , vol. 35, p. 3393 - 3397]

Dimethyl carbonate synthesis catalyzed by DABCO-derived basic ionic liquids via transesterification of ethylene carbonate with methanol

[Yang, Zhen-Zhen; He, Liang-Nian; Dou, Xiao-Yong; Chanfreau, Sebastien Tetrahedron Letters, 2010 , vol. 51, # 21 p. 2931 - 2934]

More Articles...