New Synthesis of Pinacols By Oxidative Coupling Mediated by 1, 2-Disulfides as Dehydrogenating Reagents under Irradiation.
H Fujisawa, Y Hayakawa, Y Sasaki, T Mukaiyama
Index: Fujisawa, Hidehiko; Hayakawa, Yuichiro; Sasaki, Yasuhiro; Mukaiyama, Teruaki Chemistry Letters, 2001 , # 7 p. 632 - 633
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Abstract
Thiols are generally considered hydrogen donors and their corresponding thiyl radicals play important roles not only in chemical but also in biological areas because of their character- istic behaviors.1 For example, addition reactions to the unsatu- rated carbon bonds in chemistry, and the well known “repair reactions” toward targeted carbon-centered radicals in biology.2 The abstraction of hydrogen by thiyl radicals is also well known and several examples ...
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