gem-Dihalides from α-Haloamides. II. Rearrangement of N-Bromo-α-haloamides Utilizing Bromide-82 Tracer

CL Stevens, ME Munk, AB Ash…

Index: Stevens,C.L. et al. Journal of the American Chemical Society, 1963 , vol. 85, p. 3390 - 3394

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Citation Number: 3

Abstract

Two S-brnmo-ol-haloamides were allowed to react in the presence of sodium hydroxide and bromide ion to form gem-dihalides Potassium bromide-82 was utilized internally and externally in separate experiments to establish (1) the degree of retention of bromine in the gem-dihalide product and.(2) the extent to which external bromide ion was incorporated in the gem-dihalide. With S-bromo-a-chloroisobutyramide under cold, 0', conditions, ...