Bimetallic catalysis involving dipalladium (I) and diruthenium (I) complexes

…, B Saha, SM Rahaman, JK Bera

Index: Das, Raj K.; Saha, Biswajit; Rahaman, S. M. Wahidur; Bera, Jitendra K. Chemistry - A European Journal, 2010 , vol. 16, # 48 p. 14459 - 14468

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Citation Number: 47

Abstract

Abstract Dipalladium (I) and diruthenium (I) compounds bridged by two [{(5, 7-dimethyl-1, 8- naphthyridin-2-yl) amino} carbonyl] ferrocene (L) ligands have been synthesized. The X-ray structures of [Pd 2 L 2][BF 4] 2 (1) and [Ru 2 L 2 (CO) 4][BF 4] 2 (2) reveal dinuclear structures with short metal–metal distances. In both of these structures, naphthyridine bridges the dimetal unit, and the site trans to the metal–metal bond is occupied by weakly ...