Chemische Berichte

Anodische Dimerisierung von Enoläthern

D Koch, H Schäfer, E Steckhan

Index: Koch,D. et al. Chemische Berichte, 1974 , vol. 107, p. 3640 - 3657

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Citation Number: 32

Abstract

Abstract Acht Enoläther werden in einer ungeteilten Zelle an einer Graphitanode in Methanol/2, 6-Lutidin/Natriumperchlorat in Ausbeuten zwischen 30 und 60% zu Acetalen von 1, 4-Dicarbonylverbindungen dimerisiert. Die voltammetrischen Daten: elektrochemische Reaktion 1. Ordnung bezüglich Enoläther, elektrochemische Reaktion nullter Ordnung bezüglich Methanol und n α= 1 sowie die Schwanz-Schwanz- ...

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