Exocyclic Substitution of Five-Membered Ring Chlorophosphates: A Reexamination of the rule For Nucleophilic Substitution at Phosphorus
RJP Corriu, GF Lanneau, D Leclercq
Index: Corriu, R. J. P.; Lanneau, G. F.; Leclercq, D. Phosphorus and Sulfur and the Related Elements, 1983 , vol. 18, p. 197 - 200
Full Text: HTML
Citation Number: 8
Abstract
Abstract Opposite to the SN2 (P) reactions taking place with inversion, which are highly dependent upon the nature of the nucleophile, exocyclic substitutions of five-membered ring chlorophosphates with retention show a marked kinetic levelling effect, emphasing silicon- type argumentations.
Related Articles:
[Gupta, Arvind K.; Dubey, Devendra K.; Kaushik Phosphorus, Sulfur and Silicon and the Related Elements, 2008 , vol. 183, # 7 p. 1641 - 1658]
Peracid and Acyl Peroxy Radical Mediated Oxidation and Rearrangement of Phosphoramides
[Davidson, R. Stephen; Walker, Martin D. Phosphorus and Sulfur and the Related Elements, 1987 , vol. 30, p. 305 - 310]
The reactivity of manganese diethylamide with phosphate triesters
[Fester, V. D.; Vather, S. M.; Modro, T. A. Phosphorus and Sulfur and the Related Elements, 1987 , vol. 31, p. 281 - 283]
The reactivity of manganese diethylamide with phosphate triesters
[Fester, V. D.; Vather, S. M.; Modro, T. A. Phosphorus and Sulfur and the Related Elements, 1987 , vol. 31, p. 281 - 283]
[Torii, Sigeru; Sayo, Noboru; Tanaka, Hideo Chemistry Letters, 1980 , p. 695 - 698]