Pyrolysis of Esters. XX. Pyrolysis of Cyclohexenyl Acetates1, 2

WJ Bailey, R Barclay Jr…

Index: Bailey,W.J. et al. Journal of Organic Chemistry, 1962 , vol. 27, p. 1851 - 1855

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Citation Number: 7

Abstract

Pyrolysis of methyl cis-2-acetoxy-3-cyclohexenecarboxylate at 435" produced a mixture of methyl 2, 4cyclohexadienecarboxylate, methyl 1, 3-cyclohexadienecarboxylate and methyl 1, 5-cyclohexadienecarboxyl~ te. It was shown that each of these three compounds gave this same mixture when passed through the pyrolysis tube under these indentical conditions. Reduction of this mixture of cyclohexadienecarboxvlates gave 4-methylene-2- ...