Oxidative Breakdown of Iodoalkanes to Catalytically Active Iodine Species: A Case Study in the α??Tosyloxylation of Ketones

…, O Vallcorba, A Vallribera, A Shafir, R Pleixats…

Index: Guo, Wusheng; Vallcorba, Oriol; Vallribera, Adelina; Shafir, Alexandr; Pleixats, Roser; Rius, Jordi ChemCatChem, 2014 , vol. 6, # 2 p. 468 - 472

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Citation Number: 4

Abstract

Abstract Catalysis of the oxidative processes by iodoarenes has become a promising direction in synthesis. The mechanism, involving the well-known isolable hypervalent iodine species, is generally limited to aromatic iodides, since the corresponding aliphatic species are normally highly unstable. Nevertheless, in this work catalytic amount of several primary, secondary or tertiary iodoalkanes were found to promotes the α-tosyloxylation of a range ...