Electron transfer process. 49. Radical and ionic reactions of (benzoylmethyl) mercurials
GA Russell, SV Kulkarni…
Index: Russell, Glen A.; Kulkarni, Shekhar V.; Khanna, Rajive K. Journal of Organic Chemistry, 1990 , vol. 55, # 3 p. 1080 - 1086
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Citation Number: 23
Abstract
Photolysis of PhCOCHzHgCl or (PhCOCH,) 2Hg yields benzoylmethyl radicals which can be trapped by anions such as Me2C= N02-, RC (C02Et),-, RC (O-)= CH2 or by other electron- rich systems such as (RO) 3P, N-methylpyrrole, enamines, or norbornene. Electron transfer from the adduct radicals to the mercurial yields PhCOCHzA from the anions A-, PhCOCH, P (O)(OR), from P (OR) 3, and the phenacyl derivative from N-methylpyrrole or enamines. ...
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