Preparation and Reactivity of Polystyrene-Supported Iodosylbenzene: Convenient Recyclable Oxidizing Reagent and Catalyst
…, XM Zeng, K Middleton, MS Yusubov, VV Zhdankin
Index: Chen, Jiang-Min; Zeng, Xiao-Mei; Middleton, Kyle; Yusubov, Mekhman S.; Zhdankin, Viktor V. Synlett, 2011 , # 11 p. 1613 - 1617
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Citation Number: 3
Abstract
Abstract A facile preparation of novel polystyrene-supported iodosylbenzene (PS-ISB, loading of IO up to 1.50 mmol/g) from iodopolystyrene is described. This resin has been successfully used for efficient oxidation of a diverse collection of alcohols to aldehydes and ketones in the presence of BF 3 OEt 2. PS-ISB can also be employed as efficient co-catalyst in combination with RuCl 3 in the catalytic oxidation of alcohols and aromatic ...
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