Catalytic Conversions in Water. Part 23: Steric Effects and Increased Substrate Scope in the Palladium??Neocuproine Catalyzed Aerobic Oxidation of Alcohols in …
…, M Hoogenraad, G Verspui, RA Sheldon
Index: Ten Brink, Gerd-Jan; Arends, Isabel W. C. E.; Hoogenraad, Marcel; Verspui, Goeran; Sheldon, Roger A. Advanced Synthesis and Catalysis, 2003 , vol. 345, # 12 p. 1341 - 1352
Full Text: HTML
Citation Number: 88
Abstract
Abstract The steric influence of substituents on the 2-and 9-positions of phenanthroline in the (2, 9-R 2-1, 10-phenanthroline) palladium (II)-catalyzed aerobic oxidation of 2-hexanol was investigated by means of high throughput experimentation.(Neocuproine) Pd (OAc) 2 (R [DOUBLE BOND] CH 3) was found to be a highly active catalyst for alcohol oxidation in 1: 1 water/DMSO mixtures. The catalyst is unique in that it tolerates water, polar co-solvents ...
Related Articles:
Highly Efficient AuI??Catalyzed Hydration of Alkynes
[Angewandte Chemie - International Edition, , vol. 41, # 23 p. 4563 - 4565]
[Journal of the American Chemical Society, , vol. 108, p. 536 - 538]
Reduction of ethylenic insaturations by in situ generated hydrogen
[Fort, Y.; Vanderesse, R.; Caubere, P. Chemistry Letters, 1988 , # 5 p. 757 - 760]
[Lou, Ji-Dong; Lin, Fang; Lu, Xiu Lian; Wang, Qiang; Zou, Xiao-Nan Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2012 , vol. 42, # 2 p. 282 - 284]
Oxidation of C2, C3 and higher alkanes by a ruthenium–oxo system
[Journal of the Chemical Society, Chemical Communications, , # 9 p. 943 - 944]