SULFONIUM SALT SOLVOLYSIS: PART V. MODEL SYSTEMS FOR BIOLOGICAL TRANSMETHYLATION
JB Hyne, JH Jensen
Index: Hyne,J.B.; Jensen,J.H. Canadian Journal of Chemistry, 1965 , vol. 43, p. 57 - 63
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Abstract
ABSTRACT The rates of solvolysis of a series of sulfonium salts which may be considered as models for the biologically important sulfonium salt, S-adenosylnlethionine, are discussed in terms of a possible anchimeric role of the carboxyl group of methionine in transmethylation reactions. ... INTRODUCTION In a previous paper in this series (1) the apparent enhancement of the nucleophilicity of the acetate anion in the solvolysis of dimethyl t-butyl sulfoni~im ...
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