Titanium-induced reductive elimination. Syntheses of 1, 3-dienes
HM Walborsky, HH Wüst
Index: Walborsky, H. M.; Wuest, H. H. Journal of the American Chemical Society, 1982 , vol. 104, # 21 p. 5807 - 5808
Full Text: HTML
Citation Number: 44
Abstract
OC, as determined by'H and I3C NMR spectros~ opy.~ The foregoing predictions were borne out when treatment of ketone 8 with t-BuOK (1 5 equiv) and Me1 (10 equiv) in THF at room temperature produced 11 (mp 88" C) and 12 (mp 91" C) in 68% and 17% yields, respectively, after flash chromatography. Furthermore, in accord with the previous analysis, when 12 was resubmitted to the alkylation conditions it was recovered unchanged."
Related Articles:
Ni (0)-Triphenylphosphine Complex-Catalyzed Homo-Coupling of 1-Alkenyl Halides with Zinc Powder.
[Sasaki, Ken; Nakao, Kikuji; Kobayashi, Yoshihiko; Sakai, Mutsuji; Uchino, Norito; et al. Bulletin of the Chemical Society of Japan, 1993 , vol. 66, # 8 p. 2446 - 2448]
Rearrangement of cyclopropyl, substituted vinyl and alkyl groups to divalent carbon.
[Tetrahedron Letters, , vol. 23, # 21 p. 2163 - 2166]
Reduction d'alcools alleniques par l'hydrure et le methoxy hydrure de lithium et d'aluminium
[Tetrahedron, , vol. 31, p. 383 - 389]
[Takagi; Mimura; Inokawa Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 12 p. 3517 - 3522]
[Journal of the American Chemical Society, , vol. 94, # 22 p. 7780 - 7788]