Journal of the American Chemical Society

Dependence of intramolecular dissociative electron transfer rates on driving force in donor-spacer-acceptor systems

S Antonello, F Maran

Index: Maran, Flavio; Vianello, Elio; D'Angeli, Ferruccio; Cavicchioni, Giorgio; Vecchiati, Giorgio Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1987 , p. 33 - 39

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Citation Number: 58

Abstract

The voltammetric reduction of a series of phenyl-substituted 4-benzoyloxy-1- methylcyclohexyl bromides has been investigated in DMF. The reduction leads to the cleavage of the C-Br bond. On a thermodynamic ground, the direct reduction of the tertiary C-

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