Enantioselective Rhodium??Catalyzed Addition of Potassium Alkenyltrifluoroborates to Cyclic Imines

Y Luo, AJ Carnell, HW Lam

Index: Luo, Yunfei; Carnell, Andrew J.; Lam, Hon Wai Angewandte Chemie - International Edition, 2012 , vol. 51, # 27 p. 6762 - 6766

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Citation Number: 66

Abstract

Chiral α-branched allylic amines are important building blocks for organic synthesis, and several catalytic asymmetric methods have been developed for their synthesis. For example, the enantioselective metal-catalyzed amination of allylic electrophiles [1–3] and the rearrangement of allylic imidates [4–6] have proven to be highly effective. An alternative approach to chiral allylic amines that can be advantageous from the viewpoint of ...