The Formation of Acetylenic Bond by the Elimination Reaction of Some Enol-esters. I. Syntheses of Enol-esters

M Nakagawa, G Nakaminami, F Ogura…

Index: Nakagawa,M. et al. Bulletin of the Chemical Society of Japan, 1962 , vol. 35, p. 1485 - 1487

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Citation Number: 4

Abstract

In recent years the wide distribution of various kinds of polyacetylenic compounds in the plant kingdom was well recognized15, and considerable attention has been directed towards the mode of the formation of such a labile molecule containing a large amount of energy in a living cell. The most plausible one among the proposed several hypotheses25 seems to be the dehydration mechanism of an enol of a ß-dicarbonyl compound by way of ...