Dichloromethylallyl Compounds. II. The Catalytic and Non-catalytic Substitution of Certain Chloroallylic Groups in the Ring and on the Oxygen in Phenols

DG Kundiger, H Pledger Jr

Index: Kundiger; Pledger Journal of the American Chemical Society, 1956 , vol. 78, p. 6101,6104

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Citation Number: 1

Abstract

The four allylic chlorides; 1, 1, 3-trichloro-2-methyl-l-propene, 1, 3-dichloro-2-butene, 1.3- dichloro-2-methyl-1-propene and l-chloro-2-(dichloromethylene)-cyclohexane were found to substitute into the nucleus of phenols in the absence of catalysts. 3, 3, 3-Trichloro-2-methyl-l- propene reacted with phenols in the absence of catalysts and yielded both C and 0 substituted products. The aluminum chloride catalyzed reaction between 1, 1, 3-trichloro-2 ...