Journal of Fluorine Chemistry 2018-03-27

Metal-free trifluoromethylthiolation of arenediazonium salts with Me4NSCF3

Giulia Bertoli, Benjamin Exner, Mathies V. Evers, Kristina Tschulik, Lukas J. Gooßen

Index: 10.1016/j.jfluchem.2018.03.011

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Abstract

A metal-free entry to the pharmaceutically meaningful substrate class of trifluoromethyl thioethers has been developed starting from widely available arenediazonium salts and commercially available Me4N+SCF3−. This reaction proceeds within one hour at 0 °C and is applicable to a wide range of functionalized substrates.

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