Exploratory and mechanistic studies of the electron-transfer-initiated photoaddition reactions of allylsilane-iminium salt systems

K Ohga, UC Yoon, PS Mariano

Index: Ohga, Kazuya; Yoon, Ung Chan; Mariano, Patrick S. Journal of Organic Chemistry, 1984 , vol. 49, # 2 p. 213 - 219

Full Text: HTML

Citation Number: 84

Abstract

Results Exploratory Photochemistry. Exploratory photochemical studies were conducted with l-methyl-2-phenyl-1-pyrrolinium perchlorate (4) 5 and a series of known (5-824) or easily prepared (9 and 10; see Experimental Section) allylsilanes in order to determine if the reasoning presented above is correct. Irradiation of a solution of 4 (0.01 M) and allylsilane 5 (0.88 M) in methanol y 3