The Journal of Organic Chemistry

On the palladium-catalyzed alkylation of silyl-substituted allyl acetates with enolates

BM Trost, CR Self

Index: Trost, Barry M.; Self, Christopher R. Journal of Organic Chemistry, 1984 , vol. 49, # 3 p. 468 - 473

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Citation Number: 55

Abstract

Palladium-Catalyzed Alkylation of Acetates leaving groups, the ability to manipulate the regioselectivity independent of the regiochemistry of the starting allyl system, and the obtention of a complementary stereochemistry to normal displacements combine to offer a new dimension of control. The types of allylic substituents that succumb to palladium (0) catalysts now include acetate (or other carboxylate)? vinylogous~ arbonate,~ phenoxide:~ ...