Effect of Topologically Controlled Coulombic Interactions on the Dynamic Behavior of Photoexcited Nitrophenyl Alkyl Ethers in the Presence of Tertiary Amines with …

R Gonzalez-Blanco, JL Bourdelande…

Index: Gonzalez-Blanco, Roberto; Bourdelande, Jose L.; Marquet, Jordi Journal of Organic Chemistry, 1997 , vol. 62, # 20 p. 6903 - 6910

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Citation Number: 14

Abstract

Time-resolved electronic absorption spectroscopy has been successfully applied to clarify the mechanism of the “abnormal” photochemical cleavage of 4-nitrophenyl piperidinoalkyl ethers induced by controlled Coulombic disturbance of the “normal” electronic distribution of the radical anion intermediate. Thus, photolysis of 1-piperidino-2-(2-methoxy-4- nitrophenoxy) ethane (a system with an amine with limited freedom of motion) in ...

Approaches to azepines: a new azepine by the photolysis of dimethyl p-azidosalicylate

[Mustill, Reginald A.; Rees, Alun H. Journal of Organic Chemistry, 1983 , vol. 48, p. 5041 - 5043]

Photosubstitution-photoreduction mechanistic duality in the SET photoreactions of nitrophenyl ethers with amines. The role of the steps that follow the ET

[Mir, Miquel; Marquet, Jordi; Massot, Oriol Tetrahedron, 1999 , vol. 55, # 43 p. 12603 - 12614]