Wharton fragmentation of monosulfonates of methylhexahydroindandiols

…, CJ McCloskey, D Van Derveer

Index: Caine, Drury; McCloskey, Candice J.; Derveer, Donald Van Journal of Organic Chemistry, 1985 , vol. 50, # 2 p. 175 - 179

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Citation Number: 15

Abstract

Figure 1. singlet at 6 1.18 (CDCl,) in the lH NMR spectrum for the angular methyl group. In order to verify the stereochemical assignment of this compound, a single-crystal X-ray structure determination was performed on its 2, 4-dinitrophenylhydrazone derivative. The molecular structure of this compound, as generated by ORTEP, is shown in Figure 1 with the 2, 4-dinitrophenylhydrazone group deleted.