Synthesis of 2-methylidene-1-silacyclohexanes from 2, 6-dibromohex-1-ene and polyhalosilanes
S Díez-González, L Blanco
Index: Diez-Gonzalez, Silvia; Blanco, Luis Journal of Organometallic Chemistry, 2006 , vol. 691, # 26 p. 5531 - 5539
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Citation Number: 3
Abstract
Various 2-methylidene-1-silacyclohexanes were prepared by straightforward syntheses from readily available polychloro-or polyfluorosilanes, magnesium and 2, 6-dibromohex-1-ene using Barbier-type conditions or a previously synthesized Grignard reagent. Good yields were obtained considering the low stability of the products in the reaction conditions.
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