Research Progress on Vanadium-based Cathode Materials for Sodium Ion Batteries

Qinghong Wang, jiantie Xu, Wenchao Zhang, Minglei Mao, Zengxi Wei, Chunyu Cui, Lei Wang, Yuxuan Zhu, Jianmin Ma

Index: 10.1039/C8TA01627E

Full Text: HTML

Abstract

Sodium ion batteries (SIBs) have attracted increasing attention as one of the most promising candidates for cost-effective, high-energy rechargeable batteries. Owing to their high theoretical capacity and energy density, and rich electrochemical interaction with Na+(V2+ ~ V5+), a great number of vanadium-based cathode materials, including vanadium oxides (e.g., V2O5 and VO2), vanadium bronzes (e.g., NaxVO2, NaV3O8, NaV6O15 and δ-NH4V4O10), vanadium-based phosphates (e.g., Na3V2(PO4)3, VOPO4, NaVOPO4, Na7V3(P2O7)4 and Na2(VO)P2O7) and F-containing V-based polyanion (e.g., NaVPO4F, Na3V2(PO4)2F3 and Na3(VOx)2(PO4)2F3-2x), have explored for SIBs. In this review, we mainly summarize the basic structures, modified/optimized structures, synthetic methods and morphology control of V-based cathode materials for SIBs. Additionally, major drawbacks, emerging challenges and some perspectives on the development of V-based cathode materials for SIBs are also concluded.