Addition of organosilicon halides, pseudohalides and amides to acetonitrile oxide
RF Cunico, L Bedell
Index: Cunico, Robert F.; Bedell, Louis Journal of Organometallic Chemistry, 1985 , vol. 281, p. 135 - 140
Full Text: HTML
Citation Number: 10
Abstract
Abstract The reaction of Me 3 SiX (X= Cl, I, NCS, CN, N 3 NEt 2, SMe, H (in Et 3 SiH), F, OMe, NCO, O 2 CMe) with acetonitrile oxide led to the formation of O- trimethylsilylacetohydroxamoyl adducts for the first seven members of the series. A rationale is given for the observed reactivity.
Related Articles:
O-Trimethylsilyl hydroxamoyl chlorides as nitrile oxide precursors
[Cunico, Robert F.; Bedell, Louis Journal of Organic Chemistry, 1983 , vol. 48, # 16 p. 2780 - 2782]
Preparation of 3, 4, 5??Trisubstituted 1, 2, 4??Oxadiazolium Salts from Nitrilium Salts
[Abu-El-Halawa, Rajab; Shrestha-Dawadi, Prativa Bade; Jochims, Johannes C. Chemische Berichte, 1993 , vol. 126, # 1 p. 109 - 116]