2-Carene in the Prins reaction

…, TR Urbanovich, OG Vyglazov, VA Chuiko…

Index: Manukov, E. N.; Urbanovich, T. R.; Vyglazov, O. G.; Chuiko, V. A.; Skakovskii, E. D. Chemistry of Natural Compounds, 1989 , vol. 25, p. 164 - 168 Khimiya Prirodnykh Soedinenii, 1989 , # 2 p. 193 - 198

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Abstract

Abstract The Prins reaction of 2-carene with formaldehyde has been studied. The main reaction product is 2-hydroxymethyl-3-carene. The dehydration of 2-hydroxy-methyl-3- carene is accompanied by a skeletal rearrangement of the carane structure with the formation of products having a seven-membered ring.