Tetrahedron letters

Chiral phosphine oxide BINAPO as a catalyst for enantioselective allylation of aldehydes with allyltrichlorosilanes

M Nakajima, S Kotani, T Ishizuka, S Hashimoto

Index: Nakajima, Makoto; Kotani, Shunsuke; Ishizuka, Tadao; Hashimoto, Shunichi Tetrahedron Letters, 2005 , vol. 46, # 1 p. 157 - 159

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Citation Number: 89

Abstract

The effectiveness of chiral phosphine oxide BINAPO as a catalyst for the enantioselective addition of allyltrichlorosilanes to aldehydes was demonstrated, wherein the combination of diisopropylethylamine and tetrabutylammonium iodide as additives is crucial for accelerating the catalytic cycle.