Journal of fluorine chemistry

Preparation of 2-fluoromalonic esters and related compounds from hexafluoropropene

N Ishikawa, A Takaoka, MK Ibrahim

Index: Ishikawa,N.; Takaoka,A. Journal of Fluorine Chemistry, 1984 , vol. 25, p. 203

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Citation Number: 32

Abstract

Abstract Dimethyl and diethyl fluoromalonates were prepared from hexafluoropropene by its exhaustive alcoholysis or alternatively its ammonolysis and alcoholysis. Fluoromalonates thus obtained or their alkylated derivatives were condensed with o-phenylenediamine or its substituted derivatives to give a number of 1H-3-fluoro-1, 5-dibenzodiazepin-2, 4 (3H, 5H)- diones.