The Journal of Organic Chemistry

Factors controlling the reactivity of a ligninase model based on the association of potassium monopersulfate to manganese and iron porphyrin complexes

G Labat, B Meunier

Index: Labat, Gilles; Meunier, Bernard Journal of Organic Chemistry, 1989 , vol. 54, # 21 p. 5008 - 5011

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Citation Number: 108

Abstract

Figure 1. Oxidative degradation of lignin model compounds 1 and 2 by MTPPS (free or adsorbed on Amberlite) and KHSOS. chloromethane and separated on Merck PLC plates RP-18 F mS (eluent: methanol/water, 50/50). The major products from 1 (3 and 4) or from 2 (3 and 5) were identified by'H and 13C NMR and also by mass spectrometry. They are identical with authentic samples (4 and 5 were prepared by HRP/KHS05 oxidation of 3- ...