Isolation, identification, and synthesis of compounds cosynthesized in the preparation of phencyclidine

LA Jones, RW Beaver, TL Schmoeger…

Index: Jones; Beaver; Schmoeger; et al. Journal of Organic Chemistry, 1981 , vol. 46, # 16 p. 3330 - 3333

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Citation Number: 18

Abstract

The compound following 2 in the alumina chromatographic separation proved to be l-[l-(l, l'- biphenyl-4-y1)-cyclohexyl] piperidine (6), recovered in average yields of 1%, whose'H NMR spectrum was similar to that of 2 except for the complex multiplets at 6 7.60 and 7.45 (4 H and 5 H, respectively) ascribed to the biphenyl moiety. Equally analogous to 2 was the mass spectrum of 6 which showed a molecular ion at mle 319 (55% base), an (M-1)+ ion at mle ...