Efficient thermal conversion of poly (pyridinediylbutadiynylene) s to nitrogen-containing microporous carbon
M Kijima, T Oda, T Yamazaki, Y Tazaki, J Nakamura
Index: Kijima, Masashi; Oda, Takayuki; Yamazaki, Takahisa; Tazaki, Yasunori; Nakamura, Junji Chemistry Letters, 2006 , vol. 35, # 8 p. 844 - 845
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Citation Number: 8
Abstract
Poly (pyridinediylbutadiynylene) s, a conjugated polymer alternatively consisted of the pyridine and butadiyne units, were synthesized by oxidative polycondensation of diethynylpyridine with the Hay catalyst. They converted to microporous carbons in high yields with a high efficiency of fixation of nitrogen by heating up from room temperature to 900° C under flowing of argon.
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