Evidence for concerted transfer of hydrogen from tetralin to coal based on kinetic isotope effects
KR Brower, J Pajak
Index: Brower, K.R.; Pajak, Janusz Journal of Organic Chemistry, 1984 , vol. 49, # 21 p. 3970 - 3973
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Citation Number: 17
Abstract
The H/D kinetic isotope effects for the reaction of subbituminous coal with tetralin-d12, tetralin-1, 1, 4, 4-d4, and tetralin-2,! 2, 3, 3-d4 are respectively 3.7, 2.0, and 2.0. This pattern is consistent with concerted transfer of a pair of hydrogen atoms from the 1-and 2-positions.
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