Reaction of titanocene allyls

…, JH Teuben, HJDL Meijer, EJ Kwak, AP Bruins

Index: Klei, E.; Teuben, J.H.; De Liefde Meijer, H.J.; Kwak, E.J.; Bruins, A.P. Journal of Organometallic Chemistry, 1982 , vol. 224, # 4 p. 327 - 339

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Citation Number: 53

Abstract

Abstract Cp 2 Tiη 3-allyl and Cp 2 Tiη 3-1-methylallyl react with carbon dioxide, phenylisocyanate, benzalaniline, acetone and acetonitrile to give insertion products which are formed via allyl migration. Normal insertion is observed with 2, 6 xylylisocyanide. Carbonylation of Cp 2 Tiη 3-allyl affords Cp 2 Tiη (CO) 2 and triallylmethanol. With carbon disulfide and diphenylacetylene, allyl elimination reactions are observed.