p-Methylbenzyl Hydroperoxide

EJ Lorand, EI Edwards

Index: Lorand; Edwards Journal of the American Chemical Society, 1955 , vol. 77, p. 4035

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Citation Number: 18

Abstract

p-Methylbenzyl hydroperoxide was prepared by the free radical-induced oxidation of p- xylene with molecular oxygen at 120-130”. Because of a competing reaction consisting in the fusion of two p-methylbenzyl radicals to form a crystalline hydrocarbon, the oxidation does not proceed by a chain mechanism. Isolation of the hydroperoxide was based on its solubility in dilute alkali. The hydroperoxide in a neutral solution is thermally stable up to ...