Tetrahedron Letters

Aldol reaction of aluminium enolate resulting from 1, 4-addition of Me 2 AlSPh to α, β-unsaturated carbonyl compound. A 1-acylethenyl anion equivalent

A Itoh, S Ozawa, K Oshima, H Nozaki

Index: Itoh, Akira; Ozawa, Shuji; Oshima, Koichiro; Nozaki, Hitosi Tetrahedron Letters, 1980 , vol. 21, p. 361 - 364

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Citation Number: 83

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Me 2 AlSPh or Me 2 AlSeMe adds to α,β-unsaturated carbonyl compounds in 1,4-fashion. The resulting aluminium enolates react with aldehydes effectively to afford the adducts of the title anion after formal PhSH (or MeSeH)-elimination. ... Disappearance of the starting enone ...